Biblioteca do Café

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    Application of carbon composite adsorbents prepared from coffee waste and clay for the removal of reactive dyes from aqueous solutions
    (Sociedade Brasileira de Química, 2015) Santos, Davis C. dos; Adebayo, Matthew A.; Lima, Eder C.; Pereira, Simone F. P.; Cataluña, Renato; Sauier, Caroline; Thue, Pascal S.; Machado, Fernando M.
    A novel carbon composite was prepared from a mixture of coffee waste and clay with inorganic:organic ratio of 1.3 (CC-1.3). The mixture was pyrolysed at 700 °C. Considering the application of this adsorbent for removal of anionic dyes, the CC-1.3 was treated with a 6 mol L−1 HCl for 24 h to obtain ACC-1.3. Fourier transform infrared (FTIR), N2 adsorption/desorption curves, scanning electron microscope (SEM) and powder X-ray diffractometry (XRD) were used for characterisation of CC-1.3 and ACC-1.3 carbon adsorbents. The adsorbents were effectively utilised for removal of reactive blue 19 (RB-19) and reactive violet 5 (RV-5) textile dyes from aqueous solutions. The maximum amounts of RB-19 dye adsorbed at 25 °C are 63.59 (CC-1.3) and 110.6 mg g−1 (ACC-1.3), and 54.34 (CC-1.3) and 94.32 mg g−1 (ACC-1.3) for RV-5 dye. Four simulated dye-house effluents were used to test the application of the adsorbents for treatment of effluents.